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Scanning Ka-band Doppler radar observations reveal the development and intensification of a counter-rotating vortex pair (CVP) embedded in an advancing fire-front during California’s Dixie Fire in August 2021. The observations show that an initially isolated plume associated with a new spot fire develops flow splitting and a fire-generated inflow wind on the plume’s lee side. This inflow retards the fire progression and enhances the lateral wind shear along the plume flanks. The lateral shear evolves into quasi-symmetric cyclonic and anticyclonic vortices with winds >40 m s⁻¹. This counter rotating vortex pair (CVP) spreads perpendicular to the wind direction, yielding a “y-shaped” fire perimeter, with fire intensity and direction of spread strongly linked to the vortices. Detailed snapshots of the vortices reveal associated radar hook echoes and orbiting sub-vortices of tornado-like intensity. Some vortices remain attached to the fire, while others shed downstream. Additional lidar observations show the structure and development of the fire’s inflow. We discuss the observed vortex evolution in the context of existing conceptualizations for CVPs in wildland fire, including their preferential occurrence on lee slopes and their role in generating lateral fire spread. 

Abstract Flexible metal–organic materials that exhibit stimulus-responsive switching between closed (non-porous) and open (porous) structures induced by gas molecules are of potential utility in gas storage and separation. Such behaviour is currently limited to a few dozen physisorbents that typically switch through a breathing mechanism requiring structural contortions. Here we show a clathrate (non-porous) coordination network that undergoes gas-induced switching between multiple non-porous phases through transient porosity, which involves the diffusion of guests between discrete voids through intra-network distortions. This material is synthesized as a clathrate phase with solvent-filled cavities; evacuation affords a single-crystal to single-crystal transformation to a phase with smaller cavities. At 298 K, carbon dioxide, acetylene, ethylene and ethane induce reversible switching between guest-free and gas-loaded clathrate phases. For carbon dioxide and acetylene at cryogenic temperatures, phases showing progressively higher loadings were observed and characterized using in situ X-ray diffraction, and the mechanism of diffusion was computationally elucidated. 

Abstract The capture of the xenon and krypton from nuclear reprocessing off‐gas is essential to the treatment of radioactive waste. Although various porous materials have been employed to capture Xe and Kr, the development of high‐performance adsorbents capable of trapping Xe/Kr at very low partial pressure as in the nuclear reprocessing off‐gas conditions remains challenging. Herein, we report a self‐adjusting metal‐organic framework based on multiple weak binding interactions to capture trace Xe and Kr from the nuclear reprocessing off‐gas. The self‐adjusting behavior of ATC‐Cu and its mechanism have been visualized by the in‐situ single‐crystal X‐ray diffraction studies and theoretical calculations. The self‐adjusting behavior endows ATC‐Cu unprecedented uptake capacities of 2.65 and 0.52 mmol g⁻¹for Xe and Kr respectively at 0.1 bar and 298 K, as well as the record Xe capture capability from the nuclear reprocessing off‐gas. Our work not only provides a benchmark Xe adsorbent but proposes a new route to construct smart materials for efficient separations.